Development status of domestic titanium strips

Titanium and titanium alloys are processed into products such as plates, strips, foils, tubes, rods, wires, forgings, castings, and composite materials. Titanium plates and strips are the most important product forms, but the processing of titanium plates and strips The process performance is poor, and the cutting process is difficult. In hot processing, it is very easy to absorb impurities such as hydrogen, oxygen, carbon, and nitrogen. At the same time, the wear resistance of the titanium plate and strip is poor, and the production process is complicated. Before 2007, the industrial production of titanium foil sheet in China was in a blank state. Titanium strips and coils were completely dependent on imports. The procurement costs were high, the cycle was long and the quality was unstable, which seriously affected the development of the downstream application fields of titanium strips and welded pipes. In recent years, many domestic enterprises represented by Hunan Xiangtou Jintian Technology Group have successively rolled hot-rolled titanium strips and cold-rolled titanium strips, the production technology of hot-rolled and cold-rolled pure titanium strips, and the heat treatment of strips. Technology, rolling process control technology, and other aspects have made great progress. With the acceleration of the construction of domestic nuclear power and PTA projects and the demand for localization, the demand for thin-walled titanium welded pipes, chemicals, and plates to replace titanium plates is becoming more and more strong. The total amount of processed materials is 59.2%, of which the output of titanium coils accounts for more than half. For applications in the field of nuclear power condensers and heat exchangers, the use of titanium coils has the advantages of high-quality stability, suitable for batch continuous production, short production cycle, and cost reduction compared with the use of block single sheets. The product has become the preferred material for welded pipes and plate heat exchangers for nuclear power.

Clamping and processing technology of titanium alloy parts

Titanium alloy parts have the characteristics of low density and good corrosion resistance, so they have become ideal structural materials for aerospace engineering; however, there are many factors that affect its machinability at the same time; this is because of the metallurgical properties of 6al4v titanium plate and material properties, which can have serious effects on the cutting action and the material itself.

The clamping principle of titanium alloy parts is the key technology for Grade 2 Pure Titanium Plate manufacturers to process titanium alloys, as follows:

(1) The clamping force in the roughing stage should be large to prevent the parts from loosening during the machining with large cutting force; the clamping force in the finishing stage should be small to prevent the deformation of the clamping.

(2) The clamping force acts on the rigid place, and the force is applied at as many points as possible.

(3) Appropriate auxiliary devices should be added for thin-walled structural parts with poor rigidity to increase the rigidity of the entire processing system.

Antioxidant and flame retardant coating for titanium alloys

At room temperature, a dense oxide film can be formed on the surface of titanium alloy, so it has good room temperature corrosion resistance. Titanium alloy parts used in some aerospace vehicles need to be used at medium or even high temperatures, and the oxide film formed under this condition is porous TiO2, which cannot effectively resist the inward diffusion of oxygen atoms. On the other hand, the ignition point of titanium alloys is lower than the melting point. When the titanium alloy parts of the aero-engine moving at high speed are displaced due to some reasons (such as deformation, fracture, etc.), the relative movement between the parts (such as rotating the stator) high-speed friction, and heat may ignite the Gr5 Ti-6Al-4V Titanium Sheet and cause a titanium fire accident, which seriously endangers the aviation industry. Safe use of spacecraft. Therefore, the development of titanium alloy anti-oxidation coatings and flame retardant coatings has been actively carried out at home and abroad. It is a reliable method to change the oxidation and temperature rise mechanism of titanium alloy surfaces with two types of coatings.

How to deal with the surface defect reaction layer of titanium plate and titanium rod

The surface reaction layer of Gr5 Ti-6Al-4V Titanium Plate and medical titanium rod is the main factor affecting the physical and chemical properties of titanium workpiece. Before processing, the surface pollution layer and defect layer must be completely removed. Physical and mechanical polishing of titanium plate and titanium rod surface polishing process:

1. Sandblasting:

The sandblasting treatment of titanium wire castings is generally better to use white corundum, and the sandblasting pressure is smaller than that of non-precious metals, generally controlled below 0.45MPa. Because, when the injection pressure is too large, the sand particles impact the titanium surface to generate intense sparks, and the temperature rise can react with the titanium surface, resulting in secondary pollution and affecting the surface quality. The time is 15-30 seconds, and only the sticky sand, surface sintered layer, and part of the oxide layer on the surface of the casting can be removed. The rest of the surface reaction layer structure should be quickly removed by chemical pickling.

2. Pickling:

Pickling can quickly and completely remove the surface reaction layer without contamination of the surface with other elements. Both HF-HCL series and HF-HNO3 series pickling liquids can be used for titanium pickling, but HF-HCL series pickling liquids have a large amount of hydrogen absorption, while HF-HNO3 series pickling liquids have a small hydrogen absorption capacity, which can control HNO3 The concentration of HF can reduce the absorption of hydrogen, and the surface can be brightly treated. Generally, the concentration of HF is about 3%-5%, and the concentration of HNO3 is about 15%-30%.

What are the applications of titanium wire and titanium alloy wire

Titanium and titanium alloy materials, as the leader in metal materials, have a series of excellent properties unmatched by other metal materials, so they have developed rapidly in recent years and have been rapidly and widely used in high-tech fields such as aerospace and military industry. Titanium wire manufacturers from the United States, Russia, Japan, China, and other countries in the world attach great importance to the research and development of titanium alloys, constantly develop new titanium alloy materials, and expand the application of titanium and titanium alloys. Due to the continuous in-depth research and the increase in product series, many titanium products, such as titanium wire, have also increasingly entered the field of various consumer goods.

1. Classification of Gr5 Ti-6Al-4V Titanium Wire

Titanium can be divided into pure titanium and titanium alloy according to whether it contains alloying elements, and titanium alloy can be divided into α titanium alloy and near α type alloy, (α+β) type alloy, and near β type alloy according to the difference of its composition and room temperature structure. Alloys and beta alloys. According to the different properties of titanium and titanium alloys, wires with different requirements can be prepared. Titanium and titanium alloy wire products are generally hard (Y) and annealed (M).

2. Application of surgical medical titanium wire

Pure titanium wire has a series of important properties such as good corrosion resistance, high specific strength, non-magnetic, high biocompatibility, low impedance to ultrasonic waves, high sound transmission coefficient, hydrogen storage and better shape memory function. The excellent characteristics of use-value have produced important uses in many fields such as aerospace, petrochemical, medical and health care, automobiles, construction, and sports and leisure products.

Titanium and titanium alloy wire, as an important variety of titanium material series, has developed by leaps and bounds in terms of output, specification, and application. In general, titanium and titanium alloy wires refer to titanium products supplied in the form of discs. Titanium wire processing manufacturers also supply them in the form of straight wires. In terms of diameter size, the division of rods and wires is not strict, and countries also different. And in recent years, due to its continuous development, the variety has become more and more diverse, which provides more choices in high-performance industrial and consumer products.

Application of Titanium and Titanium Alloys

Titanium metal has become one of the most important anti-corrosion materials in chemical equipment and has established its anti-corrosion position in chemical equipment. As an ideal material in chemical equipment, titanium has also attracted more and more attention from engineers and technicians. After years of implementation, titanium and its alloys have been widely used in chemical production as an excellent corrosion-resistant structural material. Now the use of titanium equipment has expanded from the initial "soda ash and caustic soda industry" to chlorate, ammonium chloride, urea, organic compounds, dyes, inorganic salts, pesticides, constituent fibers, fertilizers, fine chemicals, and other industries. It has developed from small and single to large and diversified. The tool chemical sector estimates that the chemical industry will use more than 1,500 tons of titanium. Now, among the domestic chemical titanium equipment, the largest number is the heat exchanger, followed by the titanium anode and container. The query results show that titanium heat exchangers account for 56.66%, titanium anodes account for 20.41%, titanium containers account for 16.28%, and others account for 6.65%. The earliest and largest use of ASTM B861 25*1.2mm Titanium Tube For Chemical in the chemical industry is the Chlor-alkali industry. Now there are nearly 200 large, medium, and small Chlor-alkali plants in the country, most of which use titanium anode cells and ion membrane cells to produce caustic soda, so the equipment uses a large amount of titanium. Soda ash, also known as sodium carbonate, is one of the basic chemical materials. The methods of producing soda ash mainly include the trona method, ammonia-alkali method, and the combined alkali method using salt as raw material. Regardless of which process is used, the equipment will be severely corroded by media such as sodium chloride and ammonium chloride.

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