Application of Titanium and Titanium Alloys in Vacuum Salt Production Equipment

In the vacuum salt making system, the raw material is brine, which contains a large amount of corrosive medium. Its main equipment, such as brine preheaters, heaters, and evaporation tanks, are exposed to high-concentration brine for a long time at relatively high temperatures, and are constantly impacted by salt and sand. Under such conditions, the equipment must operate normally for a long time, and anti-corrosion is the key. question.

There are many reasons for corrosion, among which the presence of O2, high temperature, Cl- and solid salt washout are the main factors. Commonly used anti-corrosion methods include deoxidation, pH adjustment, electrochemical protection, coating protection, and the use of anti-corrosion materials. Among them, the use of anti-corrosion materials is a very effective way of anti-corrosion, and the application of titanium and titanium alloys in vacuum salt production is one example.

Preheater

The raw material needs to be preheated before entering the heater to save energy. The preheater used to be a tube-and-tube heat exchanger. The heat exchange tube material was made of carbon steel, which was easy to block and corrode through the tube. The heat exchange tube was often replaced and the production was stopped for maintenance, which brought great inconvenience to production. There are also preheaters that use red copper tubes, the corrosion still exists, the service life is extended to 1 year, but it is still very short, and the cost of copper tubes is high.

Until the advent of titanium plate heat exchangers. The heat exchange surface of the plate heat exchanger is a plate, although the strength is not as good as that of the tubular heat exchanger, but its heat transfer effect is good, the material is small, the weight is light, and it is easy to maintain, and its service life can reach 15 years. For example, and the Gr9 Ti-3Al-2.5V Titanium Sheet is still as bright as new, and has never been replaced, and the economic benefits are obvious.

heater

Since the heat exchange tubes of the heater are densely arranged on the tube sheet, maintenance and repairs are quite time-consuming, and all the heating tubes need to be replaced once a year. The temperature of effect II and effect III is lower, and the heating tube can be used for about 2 years. The temperature of the IV effect is the lowest and it can only be used for 4 years and needs to be replaced. During the overhaul, the shutdown delays the production, the output is reduced, the production is seriously affected, and the maintenance cost is high (some manufacturers use red copper for the heating room, the situation has improved, but the I effect is used. The period is no more than 3-5 years). In view of the characteristics of titanium, if titanium is used in heaters, the situation will be greatly improved.

Target performance requirements

The target restricts the physical and mechanical properties of the sputtered film and affects the quality of the coating. Therefore, the target quality evaluation is relatively strict, and the following requirements should be met:

1) Low impurity content and high purity. The purity of the target material affects the uniformity of the film.

2) High density. The high-density target has the advantages of good electrical conductivity, good thermal conductivity, and high strength. Using this target for coating, the sputtering power is small, the film-forming rate is high, the film is not easy to crack, the Ti-Al Sputtering Target has a long service life, and the resistivity of the sputtered film is high. low, high transmittance.

3) The composition and structure are uniforms. The uniform target composition is an important guarantee for stable coating quality.

4) The grain size is small. The finer the grain size of the target, the more uniform the thickness distribution of the Titanium Sputtering Target, and the faster the sputtering rate. Because of the above-mentioned special requirements on the performance of the target, its preparation process is relatively complicated.

The main characteristics of titanium rod and titanium alloy material processing

Titanium rods and titanium alloys have high chemical activity. titanium rods and titanium alloys are prone to violent reactions with oxygen, nitrogen and other oxygen-containing gases at high temperatures. When the surface of the billet is heated in air, an oxide scale and a surface getter layer are formed. Titanium rods and titanium alloys are easy to absorb hydrogen when heated, which causes difficulties in the processing of certain types of titanium alloys.

The thermal conductivity of titanium rods and titanium alloys is poor. The thermal conductivity of titanium rods and titanium alloys is usually only 1/15 of the thermal conductivity of aluminum alloys and 1/5 of steel. The low thermal conductivity leads to a large temperature difference along the section of the ingot and the billet in the hot B inch, resulting in a large thermal stress, and cracks will be formed in severe cases, so the heating speed must be limited, and the variable temperature, deformation speed, Deformation rate, deformation equipment.

Polycrystalline transformation of titanium rods and titanium alloys. Titanium has a-β phase transition. Heating to the p temperature can significantly improve the plasticity and reduce the deformation resistance, but the deformation of the β region is not enough to obtain the organization with good performance.

The cold deformation ability of titanium alloy is low. The cold working deformation of most titanium alloys is difficult, and a little preheating (to 200~300T) can significantly reduce the deformation resistance and improve the plasticity.

Titanium is easy to bond and deform molds. This tendency is easy to deteriorate the surface quality of the processed material, and puts forward more stringent requirements for deformation tools and process lubrication.

High yield ratio and low elastic modulus. Straightening in the cold state is very difficult.

The above processing characteristics should be fully considered when formulating the production process.

Treatment method of center deviation of titanium screw

When the diameter of the titanium metric screw is less than 30mm and the center line is offset within 30mm, you can first use oxyacetylene to bake the bolt red, and then use a sledgehammer to bend the bolt (or bend it with a jack). Prevents recovery when the bolt is tightened.

If the spacing of the Titanium Eye Bolt is not correct, you can use a sledgehammer to bend them after being baked with an oxyacetylene flame, and weld a steel plate in the middle to reinforce it, and then fill it to death in the subsequent grouting.

For large displacement of large bolts (diameter above 30mm), the bolts should be cut off first, and a steel plate should be welded in the middle of the bolts. If the bolt strength is not enough, two reinforcing steel plates can be welded on both sides of the bolt. 3 to 4 times smaller than the diameter of the bolt.

Treatment method of titanium tube surface

The alloying of the surface of the titanium alloy tube can also be called a kind of coating. Compared with the oxide coating of palladium-coated on titanium, it has the advantages of strong bonding force, wear resistance and corrosion resistance. Compared with titanium-palladium alloy, palladium has high surface content, which saves precious metal palladium, reduces cost, and also has excellent performance.

Aluminizing the surface of the titanium tube can reduce the hydrogen absorption tendency of titanium. It is a good aluminizing condition to mix 88% alumina, 4% aluminum fluoride and 8% aluminum powder and coat it on the titanium workpiece. The temperature is 810 °C . The thickness and structure of the aluminized layer depend on the holding time. Using the infiltration method to aluminize, a thin coating with a thickness of about 2 mm can be obtained by diffusion in a short time, and the bonding force is good and does not affect the mechanical properties of the substrate. The coating consists mainly of the titanium oxide phase, forming a very effective barrier against hydrogen permeation.

After the palladium is plated on the Grade 9 Ti3Al2.5V Titanium Pipe, the palladium-plated layer can be diffused to the surface area of ​​the titanium tube by heating in different ways to form a titanium-palladium alloyed layer on the surface layer, thereby improving the corrosion resistance. Heating diffusion or laser surface remelting are in principle feasible. Using a laser to irradiate the titanium surface to make it melt and condense rapidly, the pre-vacuum-deposited 150-micron palladium-plated film can be rapidly melted to form an effective palladium alloy.

Surface treatment of titanium tubes has many advantages, which can not only increase the oxidation resistance of titanium tubes, but also enhance the gloss of the surface of titanium tubes. Different titanium tube surface treatment methods will meet different performance requirements for titanium tubes, which is an important manifestation of the production and manufacturing capabilities of titanium tube manufacturers at this stage.

Precision Problems in Machining of Titanium Alloy Fasteners

In the production and processing of grade 5 titanium round rod and candied fruit, the precision requirements for machinery will be higher. In mechanical production, because the tool is in a state of working wear during each production process, and it is calibrated according to the program, the density of titanium alloy fasteners is higher, and the tool is easily worn during the machining process. Under the state, the tool is still processed according to the program, and it is easy to cause the precision of the compact part to be affected during the processing. If the precision of the fasteners is not strictly controlled within the error range during the entire processing process, the titanium tubing for bike frame and other materials cannot be tightly connected during the use process, which will have a certain impact on the subsequent use and improve The precision of titanium alloy fasteners in the machining production process is a major problem that needs to be overcome in the production process. Fastener technology products are products made in high-precision production workshops, and the connection performance of such products is better.

The effect of laser welding on the surface treatment of titanium rods!

The process parameters of laser welding are difficult to grasp because the thermal efficiency fluctuates greatly during the welding process, and the surface condition of the welded titanium rod has a great influence on the thermal efficiency: the brighter the surface, the larger the emitted laser light, and most of the laser energy is reflected on other objects. , transferred to the surrounding material or medium in the form of "heat". But thermal efficiency changes suddenly. Before the grade 5 titanium round rod is melted, only about 10%-20% of the light energy is absorbed by the titanium rod and heats the titanium rod. When the temperature rises to the melting point of the weld metal and begins to melt, the light absorption rate of the titanium rod increases sharply. that at this time, about 60%-80% of the light capacity is absorbed by the metal, and the sudden change of thermal effect can easily cause the weld to burn through.

In order to avoid or reduce this adverse effect, you can take corresponding measures, such as welding titanium rods; roughening the surface, using a pulsed laser beam; adjusting the input energy; adjusting the spot size; Pulse width and steepness.

A ruby ​​natural crystal containing aluminum oxide and dissolved with a low concentration of chromium atoms is used as the working material of the laser generator, which is called a solid-state laser generator. If CO2 is used as the working substance of the laser generator, it is called a force gas laser generator.

At present, the power of the laser welding machine is only kilowatts, and it is expensive, the welding cost is high, and the application range is not wide. It is only used for the solder joints of some tiny parts in the manufacture of some instruments and meters, especially when some solder joints are hidden and cannot be welded by ordinary welding methods. Multi-station welding is possible using laser beams, optical fibers and deflection prisms.

What are the technical requirements for titanium tubes?

The titanium tube is light in weight, high in strength and superior in mechanical properties. It is widely used in heat exchange equipment, such as shell and tube heat exchangers, coil heat exchangers, serpentine heat exchangers, condensers, evaporators and conveying pipes, etc. Many nuclear power industries use titanium tubes as standard tubes for their units. titanium seamless tubing

skills requirement:

1. The chemical composition of titanium and titanium alloy pipes shall comply with the provisions of GB/T3620.1. When the buyer re-inspects, the allowable deviation of the chemical composition of Mingkun Titanium Industry shall comply with the provisions of GB/T3620.2.

2. The allowable deviation of the outer diameter of the pipe should meet the regulations.

3. The allowable deviation of the wall thickness of the pipe should not exceed ±12.5% ​​of its nominal wall thickness. The allowable deviation of the wall thickness of the pipe does not apply to the welding seam of the titanium welded pipe. Titanium Alloy Seamless Rectangular Tube

4. The length of the pipe should meet the regulations.

5. The fixed length or multiple length of the pipe should be within the range of its indefinite length, the allowable deviation of the fixed length is +10mm, and the multiple length should also be included in the incision amount when the pipe is cut, and each incision should be 5mm. .

What are the mechanical properties of high-quality titanium rods?

Titanium is a new type of metal, and the properties of titanium are related to the content of impurities such as carbon, nitrogen, hydrogen, and oxygen. Its characteristics are high strength, high thermal strength, good corrosion resistance, good low temperature performance, large chemical activity, small thermal conductivity, and small elastic modulus.

grade 5 titanium round rod are malleable. The elongation of high-purity titanium can reach 50% to 60%, and the section shrinkage rate can reach 70% to 80%, but the strength is low (the tensile strength of titanium iodide is 2.2-2.9MPa), and it is not suitable for structural materials. The impurities in titanium have a great influence on its mechanical properties, especially the interstitial impurities oxygen, nitrogen and carbon can greatly improve the strength of titanium, and significantly reduce its plasticity. Despite the low strength of high-purity titanium, the mechanical properties of titanium-based materials are significantly enhanced by the inclusion of small amounts of impurities and added alloying elements, making their strength comparable to high-strength steels. That is to say, the good mechanical properties of titanium as a structural material are achieved by many titanium rod manufacturers by strictly controlling the appropriate impurity content and adding alloying elements.

1. Corrosion resistance Titanium metal is an emotional metal with excellent corrosion resistance. The titanium rod filter element made of titanium metal can filter in strong alkali and strong acid media. It can be widely used in the chemical industry. In the filtration of the organic lysozyme production process in the pharmaceutical industry, due to the application of organic solvents such as acetone, ethanol, butanone, etc., if a polymer filter element such as PE, PP filter element is used to filter, It is easily dissolved by these organic solvents, and the titanium rod is quite stable in the medium of organic solvents and is widely used.

2. High temperature resistance The high temperature resistance of the titanium filter element can reach 300C, which is unmatched by other filter elements. This feature is widely used in high-temperature operating environments, and the filter element of polymer material has poor temperature resistance, generally not exceeding 50°C, and its support and filter membrane will change when it exceeds 50°C, resulting in a large deviation in filtration accuracy. Even if the PTFE filter element is above 120°C and the external pressure is 0.2MPa for a long time, the phenomenon of isolation and aging will occur. The titanium rod filter element can be used in this environment for a long time without any change in its micropores and appearance. Widely used in high temperature liquid filtration, steam filtration (steam filtration in fermentation process), air filtration at room temperature, etc.

3. Super mechanical properties (high strength) The Grade 1 Titanium Bar filter element has super mechanical properties, the external pressure is 20Kg, the internal pressure destructive force is 10Kg (no joint test), so the titanium rod can be used in the process of high pressure and fast filtration. When the external pressure of other polymer filter elements exceeds 0.5MPa, the micropore size will change or even be broken down. Application, chemical fiber manufacturing, pharmaceutical and chemical industry, compressed air filtration, deep underwater air distribution, coagulant air distribution and foaming, etc.